en_tn_condensed/lev/16/21.md

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confess over him

"confess over the goat"

he must put that sinfulness on the head of the goat

Aaron's actions here were a symbolic transfer of the people's sin to the goat as a sign that the goat would bear the punishment for their guilt.

evil deeds ... rebellion ... sins

These all mean basically the same thing. Aaron is confessing every kind of sin that the people committed.